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Volume: 14 | Article ID: art00048_2
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Catalytic Dehalogenation Polymerization of 4,4′-Dihalogentriphenylamines in the Presence of a Nickel Complex
Olga K. Kocheleva
Sergey A. Lebedev
Boris V. Kotov
Eduard. S. Petrov
Alek R. Tameev
Alexey A. Kozlov
Anatoly V. Vannikov
  DOI :  10.2352/ISSN.2169-4451.1998.14.1.art00048_2  Published Online :  January 1998
Abstract

Triphenylamine oligomers (OTPAs, n=4-10) were synthesized by dehalogenation polymerization of 4,4′-dihalogentriphenylamines. The OTPAs are a white powder, which is stable on exposure to the air and soluble in benzene, chlorobenzene, chloroform and THF. The OTPAs were characterized by IR, H-NMR and UV-visible spectroscopy measurements. OTPA films prepared by casting from solutions or vapor deposition exhibit a high drift mobility of holes and accordingly double layer organic photoconductors including the OTPA layer show a high electrophotographic sensitivity.

Journal Title : NIP & Digital Fabrication Conference
Publisher Name : Society of Imaging Science and Technology
Publisher Location : 7003 Kilworth Lane, Springfield, VA 22151, USA
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 DOI 10.2352/ISSN.2169-4451.1998.14.1.art00048_2
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Olga K. Kocheleva, Sergey A. Lebedev, Boris V. Kotov, Eduard. S. Petrov, Alek R. Tameev, Alexey A. Kozlov, Anatoly V. Vannikov, "Catalytic Dehalogenation Polymerization of 4,4′-Dihalogentriphenylamines in the Presence of a Nickel Complex"  in Proc. IS&T Int'l Conf. on Digital Printing Technologies (NIP14),  1998,  pp 528 - 531,  https://doi.org/10.2352/ISSN.2169-4451.1998.14.1.art00048_2

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Copyright © Society for Imaging Science and Technology 1998
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NIP & Digital Fabrication Conference
nip digi fabric conf
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Society of Imaging Science and Technology
7003 Kilworth Lane, Springfield, VA 22151, USA
2169-4451(19980101)1998:2L.528;1-
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Articles
Catalytic Dehalogenation Polymerization of 4,4′-Dihalogentriphenylamines in the Presence of a Nickel Complex
KochelevaOlga K.
LebedevSergey A.
KotovBoris V.
PetrovEduard. S.
TameevAlek R.
KozlovAlexey A.
VannikovAnatoly V.
01011998
1998
2
528
531
1998
Triphenylamine oligomers (OTPAs, n=4-10) were synthesized by dehalogenation polymerization of 4,4′-dihalogentriphenylamines. The OTPAs are a white powder, which is stable on exposure to the air and soluble in benzene, chlorobenzene, chloroform and THF. The OTPAs were characterized by IR, H-NMR and UV-visible spectroscopy measurements. OTPA films prepared by casting from solutions or vapor deposition exhibit a high drift mobility of holes and accordingly double layer organic photoconductors including the OTPA layer show a high electrophotographic sensitivity.