In Questioned Documents Examination, the sequence of crossing lines in the intersection of handwriting and printed area can be important clues for detecting tampered documents. Recognition of such documents is a arduous task and requires people with experience and expertise. In the present work, we investigated the possibility of determining the sequence of intersecting lines between LaserJet printing and handwriting for a series of simulated laboratory specimens in the document examination using color measurement technique. The spectral reflectance curves and color coordinates of some points on and out of the cross lines were compared. Four different commercial ballpoint pens and a black toner LaserJet were used to prepare the specimens. The color change of the intersecting lines was subjectively considered through the captured images and a visual assessment process. It was also objectively determined by determining the color difference values from the colorimetric data in CIELAB and CIELCH color spaces in the visible range. The color change evaluation showed that the order in which printing or handwriting is applied alters colorimetric results. Moreover, the investigations showed small color difference values of less than 2 units between a point of printed area individually, and intersection could be applied as a tolerance limit for pass/fail judgments.