Polarizabilities and dipole moments of hole transport molecules with different mobilities were measured. The zero-field mobilities of the molecularly-doped polymers increase with increasing polarizabilities and decrease with increasing dipole moments of the dopants. Concerning molecules
with similar dipole moments, mobilities correlate well with polarizabilities. Also concerning molecules whose polarizabilities are almost equal, the correlation between mobilities and dipole moments is clear. The 3-D plot of the mobility as a function of the polarizability and the dipole moment
is nearly coplanar. Within a framework of the small polaron formalism, polarizabilities are good indices to evaluate the degree of electron cloud extension that affects transfer integral
Akiteru Fujii, Takayuki Shoda, Shinji Aramaki, Tetsuo Murayama, "The Roles of Polarizabilities and Dipole Moments in Hole Transport Processes in Molecularly-Doped Polymers" in Journal of Imaging Science and Technology, 1999, pp 430 - 436, https://doi.org/10.2352/J.ImagingSci.Technol.1999.43.5.art00006